Classification of base oils based on physical properties

Classification of base oils based on physical properties

Classification of base oils based on physical and chemical properties in API

Base oils are very different from each other in molecular components and therefore in physical and chemical properties (eg viscosity-temperature properties). For this reason, in 1993, the American Petroleum Association (API) designed an oil classification system and divided all base oils into 5 groups based on the weight percentage of saturated compounds, the weight percentage of sulfur, and the viscosity index, as shown in the table below. It should be noted that the base oil is classified only on the basis of physical and chemical properties and not on the basis of production method. This means that the production method alone does not reflect the level of quality of the base oil. To improve the quality of the base oil, the percentage of unsaturated compounds and sulfur in it should be reduced and the viscosity index of the oil should be increased. To achieve this goal, various refining processes are used By moving from group I to III, the percentage of paraffins increases. Group 1 base oils are different from Group 2 and Group 3 has significantly less impurities (less than 30 ppm sulfur and less than 10% unsaturated compounds) and base group oils (Group 3) are somewhat pure. Which are almost colorless. Group 3 oils are also called conventional oils or base oils with very high viscosity index (VHVI). Group 4 includes all polyalphaolefins (PAOs) that are used in pure form as well as mixed with mineral base oils for lubrication conditions. Group 5 includes all other base oils, including all naphthenic base oils, medium viscosity paraffin oils, and synthetic liquids such as esters, silicones, polyglycols, and vegetable oils.

Group I base oils

  • They are produced based on old Solvent Refining and Solvent Dewaxing technologies.
  • They are obtained by solvent extraction method.
  • It is obtained from the refining of crude oil

Group II

  • It is obtained from the refining of crude oil
Group III
  • It is obtained from the refining of crude oil.
  • It is the group on which the most process has been done
  • It is the most expensive
  • It has the highest yield among mineral oils derived from crude oil
  • It uses hydroprocessing production technology and their VI or viscosity index is greater than 120.
  • Group III base oils, which are produced by intense hydrocracking or hydroisomerization, have properties very close to Group IV synthetic oils, and lubricant manufacturers can use the word “synthetic” on products made with these base oils.
Group IV base oils
  • It is composed of polyalphalephins (PAOs).
  • They are synthetic (PAO) and are made chemically
Group V
  • May contain low quality base material such as naphthenic or high quality such as esters
  • Esters, glycols and other base oils that do not meet the specifications of the first four groups are in group V of this classification.
  • Petroleum oils, the index of which is low due to the low percentage of paraffin in their composition, are also included in this group.
  • Naphthenic base oils are produced from crude oils that do not contain paraffin and have a high percentage of naphthenic materials (saturated rings). Only a few oil fields in the world can extract crude oil.